Bonding theories in coordination chemistry

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This question for SKT3023 Inorganic Chemistry

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Elmira Usak

Malasia

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Froggy Jumps Bonding theories in coordination chemistryVersión en línea This question for SKT3023 Inorganic Chemistry por Elmira Usak 1 A coordination complex has coordination number of 3. What is the expected geometry of hybrid orbitals? a Tetrahedral b Linear c Trigonal planar 2 When central metal ion has coordination number 6, what type of geometric shape will expected? a b c 3 What coordination number base of the geometric shape? a 1.Octahedral 2. Trigonal Planar 3. Linear b 1. Trigonal planar 2. Octahedral 3. trional Bipyramidal c 1. Linear 2. Trigonal Planar 3. Octahedral 4 Place ligands in spectrochemical series from weaker to stronger field: I-, Br-, Cl-, F-, CN-. a I- < Br- < Cl- < F- < CN- b I- < Cl- < Br- < F- < CN- c CN- < F- < Cl- < Br- < I- 5 The 18-electron rule applies best to which type of complexes? a Organometallic and many low-spin transition-metal complexes b Only high-spin complexes c All coordination compounds 6 Jahn-Teller distortion occurs due to degeneracy in which situations? [Image: Jahn-Teller cartoon] a Only tetrahedral complexes b d9 or other degenerate electronic configurations in octahedral systems c Never occurs in coordination chemistry 7 In octahedral MO theory, which orbitals form the t2g set? a dxy, dxz, dyz b dx2-y2, dz2 c eg set with dxy, dxz, dyz 8 What is Δo in crystal field terms? a Crystall field splitting energy between t2g and eg sets b Ligand field splitting between s and p c Total energy of all electrons in complex 9 Electronic transitions responsible for color in octahedral complexes involve which orbitals? a eg to t2g transitions b t2g to eg transitions c s to p transitions in ligands 10 [Fe(CN)6]4- is typically low-spin or high-spin in CN- field? a Low-spin in the strong CN- field b Cannot be determined from CN- field c High-spin

Froggy Jumps

Bonding theories in coordination chemistryVersión en línea

This question for SKT3023 Inorganic Chemistry

por Elmira Usak

A coordination complex has coordination number of 3. What is the expected geometry of hybrid orbitals?

Tetrahedral

Linear

Trigonal planar

When central metal ion has coordination number 6, what type of geometric shape will expected?

What coordination number base of the geometric shape?

1.Octahedral 2. Trigonal Planar 3. Linear

1. Trigonal planar 2. Octahedral 3. trional Bipyramidal

1. Linear 2. Trigonal Planar 3. Octahedral

Place ligands in spectrochemical series from weaker to stronger field: I-, Br-, Cl-, F-, CN-.

I- < Br- < Cl- < F- < CN-

I- < Cl- < Br- < F- < CN-

CN- < F- < Cl- < Br- < I-

The 18-electron rule applies best to which type of complexes?

Organometallic and many low-spin transition-metal complexes

Only high-spin complexes

All coordination compounds

Jahn-Teller distortion occurs due to degeneracy in which situations? [Image: Jahn-Teller cartoon]

Only tetrahedral complexes

d9 or other degenerate electronic configurations in octahedral systems

Never occurs in coordination chemistry

In octahedral MO theory, which orbitals form the t2g set?

dxy, dxz, dyz

dx2-y2, dz2

eg set with dxy, dxz, dyz

What is Δo in crystal field terms?

Crystall field splitting energy between t2g and eg sets

Ligand field splitting between s and p

Total energy of all electrons in complex

Electronic transitions responsible for color in octahedral complexes involve which orbitals?

eg to t2g transitions

t2g to eg transitions

s to p transitions in ligands

[Fe(CN)6]4- is typically low-spin or high-spin in CN- field?

Low-spin in the strong CN- field

Cannot be determined from CN- field

High-spin

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Bonding theories in coordination chemistry

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Bonding theories in coordination chemistryVersión en línea

por Elmira Usak

A coordination complex has coordination number of 3. What is the expected geometry of hybrid orbitals?

When central metal ion has coordination number 6, what type of geometric shape will expected?

What coordination number base of the geometric shape?

Place ligands in spectrochemical series from weaker to stronger field: I-, Br-, Cl-, F-, CN-.

The 18-electron rule applies best to which type of complexes?

Jahn-Teller distortion occurs due to degeneracy in which situations? [Image: Jahn-Teller cartoon]

In octahedral MO theory, which orbitals form the t2g set?

What is Δo in crystal field terms?

Electronic transitions responsible for color in octahedral complexes involve which orbitals?

[Fe(CN)6]4- is typically low-spin or high-spin in CN- field?

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